You gain a +2 bonus on Deception, Persuasion, and Insight checks made against denizens of that archdevil's layer, but take a -2 penalty on the same checks made against denizens of other layers. In addition, you gain a +2 bonus on Intimidate checks. The brand of Asmodeus fills you with power and authority. Three times per day as a swift action, you can use command, as the spell, as a spell-like ability.
Once a character gains a brand of the Nine Hells, it can never gain the brand of another archdevil. Nondevils can gain this feat, and the feats that require it as a prerequisite, by performing a particularly useful act for an archduke of Hell. This option is unavailable to player characters (unless a DM rules otherwise).
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